The Nitro Group in Organic Synthesis.pdf

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THE NITRO GROUP IN
ORGANIC SYNTHESIS
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ORGANIC NITRO CHEMISTRY SERIES
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THE NITRO GROUP IN
ORGANIC SYNTHESIS
Noboru Ono
A JOHN WILEY & SONS, INC., PUBLICATION
New York Chichester
Weinheim Brisbane Singapore
Toronto
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CONTENTS
Series Foreword
ix
Preface
xi
Acknowledgments
xiii
Abbreviations
xv
1. Introduction
1
2.
Preparation of Nitro Compounds
3
2.1
Nitration of Hydrocarbons / 3
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Synthesis of Nitro Compounds by Oxidation / 20
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The Nitro-Aldol (Henry) Reaction
30
3.1 Preparation of
-Nitro Alcohols / 31
3.2 Derivatives from
β
-Nitro Alcohols / 38
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3.3
Stereoselective Henry Reactions and Applications to Organic Synthesis / 51
4. Michael Addition
70
4.1
Addition to Nitroalkenes / 70
v
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