glukoneogeneza i glikoliza.pdf

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MM10__GL.pdf

GLUCONEOGENESIS & GLYCOLYSIS

(HIGH) BLOOD GLUCOSE

Liver Cell Membrane

GLUCOSE

REACTANTS

PRODUCTS

REACTANTS

PRODUCTS

Gluco s e

Glucose

ATP

P i

2.7.1.1

Hexokina s e (D) or (IV) (Glucokinase)

3.1.3. 9

ADP

H 2

Glucos e -6- P

ROUGH ENDOPLASMIC RETICULUM

5.3.1.9 5 .3.1.9

Fru c tose-6-

P

ATP

P i

3.1.3.11

2.7.1.11

H 2

ADP

Fructose- 1 ,6-bis-

P

4.1.2.13

2P i

2NAD +

Trios e -3-

P

2P i

+

2NAD

2NADH+2H

+

1.2.1.12

1.2.1.12

2NADH+2H +

2 1,3-bis-

P

- Glycerate

2 A D P

2ADP

2.7.2 .3 2.7.2.3

2ATP

2ATP

2 3- -Glycerate

P

5. 4 .2.1

2H 2 O

GLUCOSE

2 2- -Gly c erate

P

4.2.1.11

2ADP

2ATP

CORI CYCLE

2H 2 O

2.7.1.40

2CO 2

2 P -enolpyruvate

2PYRUVATE

LACTATE

2

GDP

4.1.1.32

2GTP

2Oxaloacetate

2NADH+ 2H +

Amino Acid

2-Oxo acid

1.1.1.37

2NAD

2Malate

Aspartate

2 PEP

Mitochondrial Inner Membrane

Mitochondrial Matrix

- OOCC H (O H )CH 2 COO -

Aspartate

2 PEP

2Malate

2NA D +

2-Oxo acid

2CO 2

1.1.1.37

2NADH+2H +

Amino Acid

- OOCCOCH 2 COO -

2

GDP

4.1.1.32

2 Oxaloacetate

2ATP 2ADP+ 2P i

2GTP

2H 2 O

6.4.1.1

2CO 2

2 PYRUVATE

CH 3 COCOO -

- OOCCH 2 CH 2 COO -

Succinyl-CoA

PYRUVATE

PYRUVATE

6.2.1.17

6.4.1.3

2NADH+2H

5.4.99.2

1.1.1.27

2NAD

CH 3 C H 2 COO -

Alanine

CH 3 C H (O H ) COO -

Propionate

Cytosol

Liver Cell Membrane

LACTATE

ENZYMES

1.1.1.27 Lactate dehydrogenase (only in cytosol) 4.1.1.32 Phosphoenolpyruvate carboxykinase

1.1.1.37 Malate dehydrogenase

GLUCOSE

4.1.2.13 Fructose-bisphosphatealdolase

L

C

N

O

E

E

I

S

1.2.1.12 Glyceraldehyde-3- P dehydrogenase

4.2.1.11 Phosphopyruvate hydratase

*

2.7.1.1 Hexokinase

5.3.1.9 Glucose-6-phosphate isomerase

M

U

S

C

L

E

2.7.1.30 Glycerolkinase

5.4.2.1 Phosphoglycerate mutase

2.7.1.11 6-Phosphofructokinase

5.4.99.2 Methylmalonyl-Co mutase

2.7.1.40 Pyruvate kinase

6.2.1.17 Propionate-CoA ligase

2.7.2.3 Phosphoglycerate kinase

**

6.4.1.1 Pyruvate carboxylase (only in mitochondria)

3.1.3.9 Glucose-6-phosphatase

6.4.1.3 Propionyl-CoA carboxylase

3.1.3.11 Fructose-bisphosphatase

LACTATE

Liver Hexokinase is Hexokinase D (or IV) (Often called Glucokinase)

c 2001 IUBMB

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