Physical Properties of Polymers Handbook(Springer2006).pdf

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Physical
Properties
of Polymers
Handbook
Second Edition
Physical
Properties
of Polymers
Handbook
Second Edition
Edited by
James E. Mark
Polymer Research Center and
Department of Chemistry
University of Cincinnati
Cincinnati, Ohio
888234395.001.png
Editor:
James E. Mark
Distinguished Research Professor
Department of Chemistry
Crosley Tower, Martin Luther King Drive
University of Cincinnati
Cincinnati, OH 45221-0172
markje@email.uc.edu
Library of Congress Control Number: 2005938500
ISBN-13: 978-0-387-31235-4
eISBN-13: 978-0-387-69002-5
ISBN-10: 0-387-31235-8
eISBN-10: 0-387-69002-6
Printed on acid-free paper.
2007 Springer Science þ Business Media, LLC
All rights reserved. This work may not be translated or copied in whole or in part
without the written permission of the publisher (Springer Science þ Business Media,
LLC, 233 Spring Street, New York, NY 10013, USA), except for brief excerpts in
connection with reviews or scholarly analysis. Use in connection with any form of
information storage and retrieval, electronic adaptation, computer software, or by
similar or dissimilar methodology now known or hereafter developed is forbidden.
The use in this publication of trade names, trademarks, service marks and similar
terms, even if they are not identified as such, is not to be taken as an expression of
opinion as to whether or not they are subject to proprietary rights.
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Contents
Contributors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
xi
Preface to the Second Edition
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
xvii
Preface to the First Edition
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
xix
PART I. STRUCTURE
1.
Chain Structures
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3
P. R. Sundararajan
2.
Names, Acronyms, Classes, and Structures of Some Important Polymers
. . . . . . . . . . . . . . . . . . . . . . .
25
Chandima Kumudinie Jayasuriya and Jagath K. Premachandra
PART II. THEORY
3.
The Rotational Isomeric State Model
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
43
Carin A. Helfer and Wayne L. Mattice
4.
Computational Parameters
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
59
Joel R. Fried
5.
Theoretical Models and Simulations of Polymer Chains
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
67
Andrzej Kloczkowski and Andrzej Kolinski
6.
Scaling, Exponents, and Fractal Dimensions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
83
Mohamed Daoud, H. Eugene Stanley, and Dietrich Stauffer
PART III. THERMODYNAMIC PROPERTIES
7.
Densities, Coefficients of Thermal Expansion, and Compressibilities
of Amorphous Polymers
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
93
Robert A. Orwoll
8.
Thermodynamic Properties of Proteins . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
103
George I. Makhatadze
9.
Heat Capacities of Polymers
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
145
Jianye Wen
10.
Thermal Conductivity
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
155
Yong Yang
v
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vi
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C ONTENTS
11.
Thermodynamic Quantities Governing Melting
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
165
L. Mandelkern and R. G. Alamo
12.
The Glass Temperature
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
187
Donald J. Plazek and Kia L. Ngai
13.
Sub- T g Transitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
217
Joel R. Fried
14.
Polymer—Solvent Interaction Parameter x ..................................................
233
Robert A. Orwoll and Pamela A. Arnold
15.
Theta Temperatures
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
259
P. R. Sundararajan
16.
Solubility Parameters
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
289
W. Zeng, Y. Du, Y. Xue, and H. L. Frisch
17.
Mark—Houwink—Staudinger—Sakurada Constants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
305
W. Zeng, Y. Du, Y. Xue, and H. L. Frisch
18.
Polymers and Supercritical Fluids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
319
Annette D. Shine
19.
Thermodynamics of Polymer Blends
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
339
Hany B. Eitouni and Nitash P. Balsara
PART IV. SPECTROSCOPY
20.
NMR Spectroscopy of Polymers
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
359
Alan E. Tonelli and Jeffery L. White
21.
Broadband Dielectric Spectroscopy to Study the Molecular Dynamics
of Polymers Having Different Molecular Architectures
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
385
F. Kremer
22.
Group Frequency Assignments for Major Infrared Bands Observed
in Common Synthetic Polymers
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
395
I. Noda, A. E. Dowrey, J. L. Haynes, and C. Marcott
23.
Small Angle Neutron and X-Ray Scattering . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
407
George D. Wignall
PART V. MECHANICAL PROPERTIES
24.
Mechanical Properties
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
423
Witold Brostow
25.
Chain Dimensions and Entanglement Spacings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
447
L. J. Fetters, D. J. Lohse, and R. H. Colby
26.
Temperature Dependences of the Viscoelastic Response of Polymer Systems
. . . . . . . . . . . . . . . . . . .
455
K. L. Ngai and D. J. Plazek
27.
Adhesives
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
479
Alphonsus V. Pocius

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